Espeon and Umbreon Gold Star POP Series 5Ī pair of Gold Star Pokémon cards from one of the most valuable Pokémon sets of all time Whether you’re curious how much your own card collection is worth, wondering if that rare card is really that rare or just wanting to gaze in amazement at the thousands and millions of dollars dropped on a piece of cardboard, this list of the top 23 rare and most expensive Pokémon cards will have you covered.Ģ3. 2001 Japanese Neo Summer Battle Road National No.Gyarados 64 Mario Stadium Best Photo Contest.To see this content please enable targeting cookies.